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سنتز نانوذرات متخلخل سیلیکا از پوسته شلتوک برنج به روش تخریب حرارتی | ||
| تحقیقات مهندسی صنایع غذایی | ||
| مقاله 10، دوره 21، شماره 2 - شماره پیاپی 73، دی 1401، صفحه 115-134 اصل مقاله (844.71 K) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22092/fooder.2023.356712.1319 | ||
| نویسندگان | ||
| فاطمه ارمی1؛ سید مهدی جعفری* 1؛ امان محمد ضیایی فر1؛ محمد قربانی2 | ||
| 1دانشکده صنایع غذایی، دانشگاه علوم کشاورزی و منابع طبیعی گرگان، گرگان، ایران | ||
| 2گروه علوم و صنایع غذایی، دانشکده صنایع غذایی، دانشگاه علوم کشاورزی و منابع طبیعی گرگان | ||
| چکیده | ||
| برنج یکی از اقلام غذایی مهم است که پسماند کشاورزی حاصل از آن پوستۀ شلتوک است. بخش عمدۀ خاکستر پوستۀ شلتوک (87-98 درصد) از سیلیکا تشکیل شده است و به کار بردن آن به عنوان ماده اولیه سنتز سیلیکا، در مقایسه با روش‌های دیگر، باعث کاهش آلودگی محیط‌زیست و کاهش مصرف انرژی می‌شود. پوستۀ شلتوک به علت داشتن هزینۀ پایین برای تولید سیلیکا، از نظر اقتصادی با صرفه استسیلیکا با دارا بودن ویژگی‌های منحصر به‌فرد همچون سطح ویژه بالا و تخلخل یکنواخت به عنوان نانوحامل در نانوریزپوشانی ترکیبات زیست‌فعال غذایی و دارویی کاربرد دارد. در این پژوهش، با هدف سنتز نانوذرات متخلخل سیلیکا از پوستۀ شلتوک به روش تخریب حرارتی، متغیر دمای کلسینه شدن در سه سطح 400، 600 و 800 درجه سلسیوس و متغیر دمای گلیسرول در سه سطح 200، 225، 250 درجه سلسیوس در نظر گرفته شد. نمونه سیلیکای کلسینه شده در دمای 600 درجه سلسیوس و دمای گلیسرول 200 درجه سلسیوس که دارای درصد خلوص بالا (حاوی 94/07 درصد سیلیکا) و ساختار بیشکل بود (2θ =22)، به عنوان نمونه مناسب در نظر گرفته شد. از روش سطح پاسخ نیز برای تعیین نمونه بهینه استفاده گردید. اندازۀ ذرات با استفاده از روش پراکندگی نور دینامیکی (DLS)، 252 نانومتر تعیین شد و ناحیۀ سطح ویژۀ آن 51/653 متر مربع بر گرم بود. | ||
| کلیدواژه‌ها | ||
| پوسته شلتوک برنج؛ نانوذرات متخلخل سیلیکا؛ کلسینه کردن | ||
| عنوان مقاله [English] | ||
| Synthesis of Mesoporous Silica Nanoparticles from Rice Husk by the Thermal Degradation Method | ||
| نویسندگان [English] | ||
| Fatemeh Erami1؛ seid mehdi jafari1؛ aman mohammad ziaiifar1؛ mohammad ghorbani2 | ||
| 1Agricultural Sciences and Natural Resources of Gorgan University ,Gorgan, Iran | ||
| 2Agricultural Sciences and Natural Resources of Gorgan University , Gorgan, Iran | ||
| چکیده [English] | ||
| Rice is one of the essential food items; the agricultural residue obtained from it is rice husk. Most of the rice husk ash (87-98%) is composed of silica. Application of rice husk as a raw material for the synthesis of silica, compared to other methods, reduces environmental pollution and energy consumption. It is also economically viable due to its low cost. Silica is used as a nanocarrier in the nanoencapsulation of bioactive and pharmaceutical compounds due to its unique properties, such as its high specific surface area and uniform porosity. For this purpose, mesoporous silica nanoparticles were synthesized from rice husk by heat degradation at three calcination temperatures of 400, 600, and 800°C and glycerol mixing temperatures of 200, 225, and 250°C. Calcined silica at 600°C and 200°C glycerol were considered the optimal samples. This sample had a high purity (containing 94.07% silica) and an amorphous structure (2θ=22). The response surface method (RSM) was used to determine the optimal sample. Moreover, its particle size was 252 nm, as determined by dynamic light scattering. In addition, its specific surface area was high (51.653 m2 g-1). | ||
| کلیدواژه‌ها [English] | ||
| Rice husk, Mesoporous silica nanoparticles, Calcination | ||
| مراجع | ||
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Acosta Romero, C. 2018. Essential oil components encapsulated in mesoporous silica supports: a bioactive properties evaluation and toxicological approach. Doctoral dissertation. Universitat Politècnica de València. An, D., Guo, Y., Zhu, Y. and Wang, Z. 2010. A green route to preparation of silica powders with rice husk ash and waste gas. Chemical Engineering Journal. 162(2): 509-514. Ashraf, M. A., Khan, A. M., Sarfraz, M. and Ahmad, M. 2015. Effectiveness of silica based sol-gel microencapsulation method for odorants and flavors leading to sustainable environment. Frontiers in Chemistry. Vol. 3. Article 42: 1-15. BernArdos, A. and KouřimsKá, L. 2013. Applications of mesoporous silica materials in food - a review. Czech Journal of Food Sciences. 31(2): 99-107. Chanphrom, P. 2007. Antioxidants and antioxidant activities of pigmented rice varieties and rice bran. Doctoral dissertation. Mahidol University. Diénert, F. and Wandenbulcke, F. 1923. Sur le dosage de la silice dans les eaux. CR Acad. Sci., Paris, 176, 1478-1480. Eaton, A. D., Clesceri, L. S., Greenberg A. E. and Franson M. 1995. Standard methods for the examination of water and wastewater. American Public Health Association. Inc., Washington, DC. Gharayloo D. and Moraddeh S. 2015. Sample preparation techniques in DLS. Iranian Journal of Laboratory Knowledge. 3(3):7- 2538-3450. (in Persian) Fan, J., Yu, C., Gao, F., Lei, J., Tian, B., Wang, L., Luo, Q., Tu, B., Zhou, W., and Zhao, D. 2003. Cubic mesoporous silica with large controllable entrance sizes and advanced adsorption properties. Angewandte Chemie International Edition, 42(27): 3146-3150. Gaber, A., Abdel-Rahim M., Abdel-Latief A. and Abdel-Salam M. N. 2014. Influence of calcination temperature on the structure and porosity of nanocrystalline SnO2 synthesized by a conventional precipitation method. Int J Electrochem Sci 9(1): 81-95. Gholami, T., Bazarganipour, M., Salavati-Niasari, M., and Bagheri, S. 2015. Photocatalytic degradation of methylene blue on TiO 2@SiO 2 core/shell nanoparticles: synthesis and characterization. Journal of Materials Science: Materials in Electronics 26(8): 6170-6177. Gu, S., Zhou J., Luo Z., Wang Q. and Ni, M. 2013. A detailed study of the effects of pyrolysis temperature and feedstock particle size on the preparation of nanosilica from rice husk. Industrial crops and products. 50: 540-549. Ha, C. T., Lien N. T. H., Anh, N. D. and Lam, N. L. 2017. Development of natural anthocyanin dye-doped silica nanoparticles for pH and borate-sensing applications. Journal of Electronic Materials. 46(12): 6843-6847. Hematkhah, H. 2019. Iran ranks 28th in rice production in the world, Research Report No. 84178961, irna.ir/news. (in Persian) Hu, G., Huang S., Cao S. and Ma Z. 2009. Effect of enrichment with hemicellulose from rice bran on chemical and functional properties of bread. Food Chemistry, 115(3): 839-842. Janatova, A., Bernardos, A., Smid, J., Frankova, A., Lhotka, M., Kourimská, L., Pulkrabek, J. and Kloucek, P. 2015. Long-term antifungal activity of volatile essential oil components released from mesoporous silica materials. Industrial Crops and Products. 67: 216-220. Khodam, F. 2018. X-ray diffraction (XRD) spectroscopy. New approaches in Iranian scientific laboratories. 2 (4): 11-19. (in Persian) Krishnarao, R., Subrahmanyam, J. and Kumar, T. J. 2001. Studies on the formation of black particles in rice husk silica ash. Journal of the European Ceramic Society. 21(1): 99-104. Lakkis, J. M. 2007. Encapsulation and controlled release technologies in food systems. Wiley Online Library. 113-133. Lee, B., Ma, Z., Zhang, Z., Park, C. and Dai, S. 2009. Influences of synthesis conditions and mesoporous structures on the gold nanoparticles supported on mesoporous silica hosts. Microporous and Mesoporous Materials. 122(1-3):160-167. Liou, T.-H. and Yang, C.-C. 2011. Synthesis and surface characteristics of nanosilica produced from alkali-extracted rice husk ash. Materials science and engineering. 176(7):521-529. Mahmud, M. S., Daud, F. D. M., Sariffudin, N., Mohd Zaki, H. H., Nordin, N. H. and Mohammad, N. F. 2022. High Purity Nano-Silica from Rice Husk Ash (RHA) via Chemical Method as Additive/Stabilizing Agent for CO2 Capture Application. Key Engineering Materials, Trans Tech Publ. 908: 373-378 Majumdar, C., Sharma, M. and Soni, G. 2014. The simple unconventional method to extract amorphous silica from rice husk. Bio Resource Technology. Musić, S., Filipović-Vinceković, N. and Sekovanić, L. 2011. Precipitation of amorphous SiO2 particles and their properties. Brazilian journal of chemical engineering. 28(1): 89-94. Nassar, M. Y., Ahmed, I. S. and Abo-Raya, M. A. 2019. A facile and tunable approach for synthesis of pure silica nanostructures from rice husk for the removal of ciprofloxacin drug from polluted aqueous solutions. Journal of Molecular Liquids. 282: 251-263. Noushad, M., Ab Rahman, I., Husein, A., Mohamad, D. and Ismail, A. R. 2012. A simple method of obtaining spherical nanosilica from rice husk. International Journal on Advanced Science, Engineering and Information Technology. 2(2): 141-143. Rahman, I. A.and Padavettan, V. 2012. Synthesis of silica nanoparticles by sol-gel: size-dependent properties, surface modification, and applications in silica-polymer nanocomposites—a review. Journal of Nanomaterials. Raiesi, F., Razavi, H., Hojjatoleslami, M., and Keramat, J. 2013. Production of healthy orange drink using rice bran extract. Iranian Journal of Nutrition Sciences and Food Industry. 7 (4): 45-53. (in Persian) Raja, S. L. 2019. Improving Porosity of Glycerol-plated Silica from Rice Husk Silica. Journal of Chemical Natural Resources. 1(2): 88-97. Sánchez‐Flores, N. A., Pacheco‐Malagón, G., Pérez‐Romo, P., Armendariz, H., Guzmán‐Castillo, M. de L, Saniger, J. M. and Fripiat, J. J. 2007. Mesoporous silica from rice hull ash. Journal of Chemical Technology and Biotechnology. International Research in Process, Environmental and Clean Technology. 82(7): 614-619. Shahbandeh, M. 2021, Rice - statistics and facts, Research Report No.1443, statista.com/topics/rice/. (in Persian) Setyawan, N. and Yuliani, S. 2021. Synthesis of silica from rice husk by sol-gel method. IOP Conference Series: Earth and Environmental Science, IOP Publishing. 733(1): 012149. Sungsopha, J., Moonngarm, A. and Kanesakoo, R. 2009. Application of germination and enzymatic treatment to improve the concentration of bioactive compounds and antioxidant activity of rice bran. Australian Journal of Basic and Applied Sciences. 3(4): 3653-3661. Suttiruengwong, S., Puathawee, P. and Chareonpanich, M. 2010. Preparation of mesoporous silica from rice husk ash: Effect of depolymerizing agents on physico-chemical properties. Advanced Materials Research.Trans Tech Publications Ltd. 93:664-667. Thommes, M., Instruments, Q. and Boynton Beach, F. 2006. Aspects of a novel method for the pore size analysis of thin silica films based on krypton adsorption at liquid argon temperature. Annual Meeting. Todkar, B. S., Deshmukh, S. and Deorukhka, O. 2016. Extraction of silica from rice husk. International Journal of Engineering Research and Development. 12(3): 69-74. Tung-Whei Chow, D., and Robinson, R. J. 1953. Forms of silicate available for colorimetric determination. Analytical Chemistry. 25(4): 646-648. Wang, S. 2009. Ordered mesoporous materials for drug delivery. Microporous and mesoporous materials 117(1-2): 1-9. Wang, W., Martin, J. C., Zhang, N., Ma, C., Han, A., & Sun, L. 2011. Harvesting silica nanoparticles from rice husks. Journal of Nanoparticle Research. 13: 6981-6990. Wee, N. N. A. N., Samsuri, A., Latif, M. N. and Yunus, W. M. Z. W. 2019. Synthesis of silica from rice husk using acid pretreatment and its characterization. AIP Conference Proceedings, AIP Publishing. Yuliani, S., Bhandari, B., Rutgers, R. and Arcy, B. D. 2004. Application of microencapsulated flavor to extrusion products. Food Reviews International. 20(2): 163-185. Zarei, V., Emamzadeh, A. and Nasiri, A. 2018. Synthesis of amorphous silica nanoparticles from natural materials and its application in drilling fluid for stabilization of Chilean layers. Petroleum Research. 27 (6-96): 18-31. (in Persian) Zuidam, N. J. and Nedović, V. 2010. Encapsulation technologies for active food ingredients and food processing. Vol. 410. New York, NY, USA: Springer. | ||
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