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کارآیی لایه‌های دوگانه هیدروکسیدی با ساختار نانو در استخراج و شناسایی ترکیب‌های فرّار گیاه افسنطین (Artemisia absinthium L.) با استفاده از روش میکرواستخراج فاز جامد در فضای فوقانی و کروماتوگرافی گازی- طیف‌سنجی جرمی | ||
| تحقیقات گیاهان دارویی و معطر ایران | ||
| مقاله 5، دوره 35، شماره 5 - شماره پیاپی 97، آذر و دی 1398، صفحه 745-758 اصل مقاله (746.13 K) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22092/ijmapr.2019.124850.2474 | ||
| نویسندگان | ||
| مرضیه باباش پور اصل* 1؛ مرضیه پیریایی2؛ ایرج فرهنگ3 | ||
| 1استادیار، گروه باغبانی، واحد مراغه، دانشگاه آزاد اسلامی، مراغه، ایران، | ||
| 2استادیار، گروه شیمی، دانشکده علوم، دانشگاه مراغه، مراغه، ایران | ||
| 3دانش‌آموخته کارشناسی ارشد، گروه بیوتکنولوژی، واحد مراغه، دانشگاه آزاد اسلامی، مراغه، ایران | ||
| چکیده | ||
| شناسه دیجیتال (DOR): 98.1000/1735-0905.1398.35.745.97.5.1603.1610 جنس آرتمیزیا شامل تعداد زیادی گونه بوده که برخی از آنها با کاربرد متنوع به‌صورت تجاری کشت می‌شوند. تجمع زیاد روغن‌های فرّار و سایر ترپنوئیدها در اعضای معینی از خانواده آستراسه مانند افسنطین (Artemisia absithium L.) سبب شده که از آنها به‌عنوان طعم‌دهنده غذا استفاده گردد. ترپنوئیدها و ترکیب‌های فنولیکی همچنین مسئول ارزش دارویی و پزشکی بسیاری از اعضای این خانواده هستند. میکرواستخراج فاز جامد (SPME) یک روش سریع، آسان، کارآمد، بی‌نیاز از حلال زیاد و با امکان اتوماسیون راحت است. در این پژوهش، میکرواستخراج فاز جامد در فضای فوقانی (HS-SPME) با استفاده از فایبر پوشش داده شده با لایه‌های دوگانه هیدروکسیدی با ساختار نانو در ترکیب با کروماتوگرافی گازی-اسپکتروفتومتری جرمی برای جمع‌آوری و ردیابی ترکیب‌های فرّار گیاه افسنطین استفاده شد. پارامترهای آزمایشی شامل درجه حرارت و زمان واجذبی، درجه حرارت و زمان استخراج، مقدار نمونه و تأثیر مقدار آب مورد آزمون قرار گرفته و بهینه‌سازی شدند. روش پیشنهادی در مقایسه با روش‌های مرسوم آنالیز ساده بوده و هزینه تجهیزات آن اندک است. همچنین در این روش، زمان آنالیز کوتاه‌تر است و می‌تواند برای آنالیز ترکیب‌های فرّار گیاهان دارویی بکار رود. | ||
| کلیدواژه‌ها | ||
| افسنطین (Artemisia absithium L.)؛ میکرواستخراج فاز جامد در فضای فوقانی؛ روغن‌های فرّار؛ لایه‌های دوگانه هیدروکسید؛ نانوساختار اکسید آلومینیوم؛ کروماتوگرافی گازی-طیف‌سنجی جرمی | ||
| عنوان مقاله [English] | ||
| Efficiency of nanostructure layered double hydroxide in extraction and identification of volatile oil constituents of Artemisia absinthium L. using headspace solid-phase microextraction method and gas chromatography-mass spectrometry methods | ||
| نویسندگان [English] | ||
| M. Babashpour-Asl1؛ M. Piryaei2؛ I. Farhang3 | ||
| 1Department of Horticulture, Maragheh Branch, Islamic Azad University, Maragheh, Iran | ||
| 2Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh, Iran | ||
| 3Department of Biotechnology, Maragheh Branch, Islamic Azad University, Maragheh, Iran | ||
| چکیده [English] | ||
| The genus Artemisia comprises a large number of species, some of which are cultivated commercially in a variety of applications. The high accumulation of essential oils and other terpenoids in certain members of family Asteraceae, such as wormwood (Artemisia absinthium L.), has made them useful as flavorings. Terpenoids and phenolic compounds are also responsible for the medicinal and medical values of many members of this family. The solid-phase microextraction (SPME) is a fast, easy, efficient, highly solvent-free, and easy-to-automate method. In the present study, headspace SPME (HS-SPME) using nanostructured layered double hydroxide coated fiber in combination with gas chromatography-mass spectrometry was utilized as a monitoring technique for the collection and detection of essential oil constituents of wormwood. Experimental parameters including temperature and desorption time, temperature and extraction time, sample weight, and water content effect were tested and optimized. A temperature of 260 °C was found to be appropriate for efficient desorption. The best desorption time was obtained 2 min for all measurements. The optimized quantities were found for extraction temperature 75 °C, extraction time 25 min, sample weight 2.5 g. The added water deactivated the fiber surface by blocking the active sites; therefore, the proposed fiber is suitable for dry samples. The proposed method is simple and costly compared to conventional methods of analysis. In addition, in this method, the analysis time is shorter and could be used for the analysis of volatile compounds in medicinal plants. | ||
| کلیدواژه‌ها [English] | ||
| Wormwood (Artemisia absithium L.), HS-SPME, essential oil, LDH, nanoporous anodic aluminum oxid, GC-MS | ||
| مراجع | ||
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