| تعداد نشریات | 286 |
| تعداد نشریات سازمان | 84 |
| تعداد شماره‌ها | 2,980 |
| تعداد مقالات | 33,446 |
| تعداد مشاهده مقاله | 43,911,891 |
| تعداد دریافت فایل اصل مقاله | 20,410,891 |
مقایسه کارایی دو جاذب‌کربن فعال و پودر چوب راش اصلاح شده با مس در حذف یون سولفید از مایع پخت سیاه خمیر کاغذ سازی کرافت | ||
| تحقیقات علوم چوب و کاغذ ایران | ||
| مقاله 6، دوره 35، شماره 4 - شماره پیاپی 73، دی 1399، صفحه 376-391 اصل مقاله (806.74 K) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22092/ijwpr.2020.343056.1617 | ||
| نویسندگان | ||
| معصومه ملایی1؛ مظاهر معین الدینی* 2؛ نعمت اله خراسانی3؛ محمد آزادفلاح4؛ امیرهومن حمصی5 | ||
| 1دانشجوی گروه تخصصی آلودگی محیط‌زیست، دانشکده منابع طبیعی و محیط‌زیست، دانشگاه آزاد اسلامی، واحد علوم تحقیقات، تهران، ایران | ||
| 2استادیار گروه تخصصی محیط‌زیست، دانشکده منابع طبیعی، دانشگاه تهران، کرج، ایران، | ||
| 3گروه محیط زیست، دانشکده منابع طبیعی، دانشگاه تهران | ||
| 4گروه علوم و صنایع چوب و کاغذ، دانشکده منابع طبیعی، دانشگاه تهران | ||
| 5عضو هیأت علمی گروه تخصصی علوم و صنایع چوب و کاغذ، دانشکده منابع طبیعی و محیط زیست، دانشگاه آزاد اسلامی، واحد علوم تحقیقات | ||
| چکیده | ||
| یون سولفید2 S-نشات گرفته از Na2S باقی مانده در مایع پخت سیاه منشا تولید گاز H2S در چرخه بازیابی مایع پخت سیاه در صنعت خمیرکاغذسازی کرافت است. در این پژوهش سعی شد با حذف یون مذکوراز این مایع با استفاده از جاذب‌های تهیه شده (Cu-PAC و Cu-BWP100) از تولید H2S جلوگیری شود. جاذب‌ها از غوطه ور نمودن کربن فعال پودری (PAC) و پودر چوب راش با مش 100 (BWP100) در محلول M1/0 از CuCl2 تولید شدند. ویژگی‌های جاذب‌ها در قبل و بعد از بارگذاری یون مس به‌وسیله آنالیزهای FTIR و BET و SEM- FEI تعیین شد. در نهایت کارایی این جاذب‌ها در حذف یون S-2 از مایع پخت سیاه با سه سطح سولفیدیته (22% و 20%، 18%) مورد بررسی قرار گرفت. نتایج حاصله از آنالیزهای FTIR و BET و SEM- FEI نشان‌دادند یون Cu+2 بدون آن‌که هیچ‌گونه تغییری در ساختار جاذب‌ها به وجود آورد، بر روی سطوح مواد آلی اولیه قرارگرفته‌اند. داده‌های آزمایشی مربوط به جاذب Cu-PAC نشان دادند که مطابقت بیشتری با معادله فرندلیچ و تبعیت بیشتری با معادله شبه درجه دوم داشت درحالیکه در مورد جاذب Cu-BWP100 این تطابق با معادله لانگمویر و تبعیت از معادله شبه درجه اول بود. جاذب Cu-PAC قابلیت حذف 93/79% و Cu-BWP10003/60% از یونS-2 را از مایع پخت سیاه دارد. جاذب Cu-PAC با داشتن سطح ویژه بیشتر توانایی بالاتری در حذف یون S-2 از مایع پخت سیاه نسبت به جاذب Cu-BWP100 دارد. در کل جاذب‌های نام برده شده با حذف یون S-2 توانایی بالایی در کاهش تولید H2S خواهند داشت. | ||
| کلیدواژه‌ها | ||
| خمیر و کاغذ کرافت؛ لیکور سیاه؛ S-2؛ جاذب‌های سنتز شده؛ H2S | ||
| عنوان مقاله [English] | ||
| Comparison of the efficiency of two adsorbents activated carbon and beech wood powder copper-modified in removing sulfide ions (S-2) from the black liquor of Kraft pulp and paper | ||
| نویسندگان [English] | ||
| Masoumeh Mollaei1؛ Mazaher Moeinaddini2؛ Nematollah Khorasani3؛ Mohammad Azadfallah4؛ Amirhooman Hemmasi5 | ||
| 1Department of Environmental science, Faculty of Natural Resources and Environment, Science and Research Branch, Islamic Azad University, Tehran, Iran | ||
| 2Department of Environmental science, Faculty of Natural Resources, University of Tehran, P.O. Box 4314, Karaj, Iran | ||
| 3Department of Environmental Science, Faculty of Natural Resources, University of Tehran | ||
| 4wood and paper science and technology department, of natural Resources faculty, university of Tehran. IRAN | ||
| 5Faculty of Natural Resources and Environment, Science and Research Branch, Islamic Azad University | ||
| چکیده [English] | ||
| Sulfide ions (S-2 ) derived from Na2S remaining in black liqueur are the source of H2S gas production along the black liquor recovery cycle in the Kraft pulp and paper industry. In this study, we tried to prevent the production of H2S by removing the mentioned ions from black liquor by using of synthesized adsorbents (Cu-PAC and Cu-BWP100). The adsorbents were produced by immersing powdered activated carbon (PAC) and beech powder with 100 mesh (BWP100) in 0.1 M solution of CuCl2. The adsorbent properties were obtained before and after copper ion loading by FTIR, BET and SEM-FEI analyses. Finally, the performance of these adsorbents in the removal of S-2 from black liquor with three levels of sulfide (22%, 20, 18) was investigated. The results of FTIR, BET and SEM-FEI analysis showed that Cu+ 2 was located on the surfaces of raw organic material without any change in the structure of them. Experimental data for the Cu-PAC adsorbent showed that it was more agreement with the Freundlich equation and more follow to the pseudo-second-order kinetic model, whereas for Cu-BWP100 adsorbent it was the more consistent with the Langmuir equation and adherence to the pseudo-first-order kinetic model. The Cu-PAC adsorbent has the ability to remove 79.93% and Cu-BWP100 60.03% of S-2 from black liquor. The Cu-PAC, with its higher specific surface area, has a higher ability to remove S-2 from the black liquor than the Cu-BWP100. In general, the mentioned adsorbents will have a high ability to reduce H2S production by eliminating S-2. | ||
| کلیدواژه‌ها [English] | ||
| kraft pulp and paper, Black liquor, S-2, synthesized adsorbents, H2S | ||
|
سایر فایل های مرتبط با مقاله
|
||
| مراجع | ||
|
-Adegoke, K.A. and Bello, O.S., 2015. Dye sequestration using agricultural wastes as adsorbents. Water Resources and Industry 12: 8-24. -Ahmed, I. and Jhung, S.H., 2015. Effective adsorptive removal of indole from model fuel using a metal-organic framework functionalized with amino groups. Journal of hazardous materials 283: 544-550. -ALOthman, Z. A. (2012). "A review: fundamental aspects of silicate mesoporous materials." Materials 5(12): 2874-2902. -Association, A.P.H., 2005. APHA (2005) Standard methods for the examination of water and wastewater. APHA Washington DC, USA. -Azimvand, J. and Mirshokraie, S.A., 2016. "Assessment of physico-chemical characteristics and treatment method of Paper Industry Effluents: a review." International Research Journal of Applied and Basic Sciences 10(1): 32-43. -Bagheri, M., M. Y. Masoomi and Morsali, A., 2017. "High organic sulfur removal performance of a cobalt based metal-organic framework." Journal of hazardous materials 331: 142-149. -Bajpai, P., 2014. Emissions from pulping. Biological Odour Treatment, Springer: 9-16. -Brown, K.A., McGreer, E.R., Taekema, B. and Cullen, J.T., 2011. "Determination of total free sulphides in sediment porewater and artefacts related to the mobility of mineral sulphides." Aquaticgeochemistry 17(6): 821-839. -Chen, Z., Ling, L., Wang, B., Fan, H., Shangguan, J. and Mi, J., 2016. "Adsorptive desulfurization with metal-organic frameworks: A density functional theory investigation." Applied Surface Science 387: 483-490. -Cherif, H., 2016. Study and modeling of separation methods H2S from methane, selection of a method favoring H2S valorization. -De Falco, G., Montagnaro, F., Balsamo, M., Erto, A., Deorsola, F.A., Lisi, L. and Cimino, S., 2018. "Synergic effect of Zn and Cu oxides dispersed on activated carbon during reactive adsorption of H2S at room temperature." Microporous and Mesoporous Materials 257: 135-146. -Hadavifar, M., Bahramifar, N., Younesi, H. and Li, Q., 2014. "Adsorption of mercury ions from synthetic and real wastewater aqueous solution by functionalized multi-walled carbon nanotube with both amino and thiolated groups." Chemical Engineering Journal 237: 217-228. -Hagga, K. and Laitinen, M., 2006. Experiences of the World’s Biggest Recovery Boiler at Jinhai Pulp & Paper Co. in Yang Pu, Hainan, China. the 7th International Colloquium on Black Liquor Combustion and Gasification, Jyvaskyla, Finland, July. -Ho, Y.-S., 2006. "Review of second-order models for adsorption systems." Journal of hazardous materials 136(3): 681-689. -Holik, H., 2006. Handbook of paper and board, John Wiley & Sons. -Hong, S., Wen, C., He, J., Gan, F. and Ho, Y.-S., 2009. "Adsorption thermodynamics of methylene blue onto bentonite." Journal of hazardous materials 167(1-3): 630-633. -Jang, H.M., Yoo, S., Choi, S., Park, and Kan, E., 2018. "Adsorption isotherm, kinetic modeling and mechanism of tetracycline on Pinus taeda-derived activated biochar." Bioresource technology 259: 24-31. -Jung, B.K. and Jhung, S.H., 2015. "Adsorptive removal of benzothiophene from model fuel, using modified activated carbons, in presence of diethylether." Fuel 145: 249-255. -Kazemi, A., Bahramifar, N., Heydari, A. and Olsen, S.I., 2019. "Synthesis and sustainable assessment of thiol-functionalization of magnetic graphene oxide and superparamagnetic Fe3O4@ SiO2 for Hg (II) removal from aqueous solution and petrochemical wastewater." Journal of the Taiwan Institute of Chemical Engineers 95: 78-93. -Khan, N.A., Hasan, Z. and Jhung, S.H., 2013. "Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): a review." Journal of hazardous materials 244: 444-456. -Khan, N.A., Hasan, Z., Min, K.S., Paek S.-M. and Jhung, S.H., 2013. "Facile introduction of Cu+ on activated carbon at ambient conditions and adsorption of benzothiophene over Cu+/activated carbon." Fuel processing technology 116: 265-270. -Khan, N.A. and Jhung, S.H., 2017. "Adsorptive removal and separation of chemicals with metal-organic frameworks: Contribution of π-complexation." Journal of hazardous materials 325: 198-213. -Kowanga, K.D., Gatebe, E., Mauti, G.O. and Mauti, E.M., 2016. "Kinetic, sorption isotherms, pseudo-first-order model and pseudo-second-order model studies of Cu (II) and Pb (II) using defatted Moringa oleifera seed powder." J Phytopharmacol 5(2): 71-78. -Kumar, A., Singh, S., Rajulapati, V. and Goyal, A., 2020. "Evaluation of pre-treatment methods for Lantana camara stem for enhanced enzymatic saccharification." 3 Biotech 10(2): 1-11. -Laplante, B. and Rilstone, P., 1996. "Environmental inspections and emissions of the pulp and paper industry in Quebec." Journal of Environmental Economics and management 31(1): 19-36. -Lee, C.-R., Kim, H.-S., Jang, I.-H., Im, J.-H. and Park, N.-G., 2011. "Pseudo first-order adsorption kinetics of N719 dye on TiO2 surface." ACS applied materials & interfaces 3(6): 1953-1957. -Li, A.-L., Gao, Q., Xu, J. and Bu, X.-H., 2017. "Proton-conductive metal-organic frameworks: Recent advances and perspectives." Coordination Chemistry Reviews 344: 54-82. -Liang, C.C.V., 2008. Reduced sulphur compounds in ambient air and in emissions from wastewater clarifiers at a Kraft pulp mill. -Lombardo, S. and Thielemans, W., 2019. "Thermodynamics of adsorption on nanocellulose surfaces." Cellulose 26(1): 249-279. -Lourençon, T.V., Hansel, F.A., da Silva, T.A., Ramos, L.P., de Muniz, G.I. and Magalhães, W.L., 2015. "Hardwood and softwood kraft lignins fractionation by simple sequential acid precipitation." Separation and Purification Technology 154: 82-88. -Ma, H., Cheng, X., Li, G., Chen, S., Quan, Z., Zhao, S. and Niu, L., 2000. "The influence of hydrogen sulfide on corrosion of iron under different conditions." Corrosion science 42(10): 1669-1683. -Pal, P., Edathil, A.A., Chaurasia, L., Rambabu, K. and Banat, F., 2018. "Removal of sulfide from aqueous solutions using novel alginate–iron oxide magnetic hydrogel composites." Polymer Bulletin 75(12): 5455-5475. -Porter, J., Sands, T. and Trung, T., 2009. Understanding the Kraft Liquor Cycle: A need for online measurement and control. TAPPI Engineering, Pulp and Environmental Conference. -Rodriguez, J.A. and Hrbek, J., 1999. "Interaction of sulfur with well-defined metal and oxide surfaces: unraveling the mysteries behind catalyst poisoning and desulfurization." Accounts of Chemical Research 32(9): 719-728. -Shen, F., Liu, J., Zhang, Z., Dong, Y. and Gu, C., 2018. "Density functional study of hydrogen sulfide adsorption mechanism on activated carbon." Fuel Processing Technology 171: 258-264. -Shu, J., Cheng, S., Xia, H., Zhang, L., Peng, J., Li, C. and Zhang, S., 2017. "Copper loaded on activated carbon as an efficient adsorbent for removal of methylene blue." RSC advances 7(24): 14395-14405. -Silva, B., Martins, M., Rosca, M., Rocha, V., Lago, A., Neves, I.C. and Tavares, T., 2020. "Waste-based biosorbents as cost-effective alternatives to commercial adsorbents for the retention of fluoxetine from water." Separation and Purification Technology 235: 116139. -Wang, M., Huang, Z.-H., Liu, G. and Kang, F., 2011. "Adsorption of dimethyl sulfide from aqueous solution by a cost-effective bamboo charcoal." Journal of hazardous materials 190(1-3): 1009-1015. -Zahid, W.M., Othman, M.A. and Abasaeed, A.E., 2017. "Enhanced sulfur removal by a tuned composite structure of Cu, Zn, Fe, and Al elements." Journal of hazardous materials 331: 273-279. -Zhang, S., Zhang, L., Lu, X., Shi, C., Tang, T., Wang, X., Huang, Q. and Zeng, H., 2018. "Adsorption kinetics of asphaltenes at oil/water interface: Effects of concentration and temperature." Fuel 212: 387-394. | ||
|
آمار تعداد مشاهده مقاله: 451 تعداد دریافت فایل اصل مقاله: 324 |
||
