| تعداد نشریات | 284 |
| تعداد نشریات سازمان | 82 |
| تعداد شماره‌ها | 3,073 |
| تعداد مقالات | 34,300 |
| تعداد مشاهده مقاله | 47,094,147 |
| تعداد دریافت فایل اصل مقاله | 78,003,784 |
عملکرد دوگانه کیتوزان در بهبود نگهداشت نانو ذرات اکسید آهن و مقاومت های مکانیکی کاغذ مغناطیسی تولید شده با فرآیند سنتز درجا | ||
| تحقیقات علوم چوب و کاغذ ایران | ||
| دوره 35، شماره 2 - شماره پیاپی 71، مرداد 1399، صفحه 205-217 اصل مقاله (1.07 M) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22092/ijwpr.2020.342131.1603 | ||
| نویسندگان | ||
| شقایق رضانژاد1؛ نورالدین نظرنژاد* 2؛ حسین رسالتی3؛ سید مجید ذبیح‌زاده4 | ||
| 1دانشجوی دکتری صنایع خمیر و کاغذ دانشگاه علوم کشاورزی و منابع طبیعی ساری | ||
| 2دانشگاه علوم کشاورزی و منابع طبیعی ساری- دانشیار گروه چوب و کاغذ | ||
| 3استاد گروه صنایع چوب و فرآورده‌های سلولزی، دانشگاه علوم کشاورزی و منابع طبیعی ساری | ||
| 4دانشیار گروه صنایع چوب و فرآورده‌های سلولزی، دانشگاه علوم کشاورزی و منابع طبیعی ساری | ||
| چکیده | ||
| مهم‌ترین چالش‌های استفاده از مواد معدنی و پرکننده در فرآیند کاغذ سازی ماندگاری کم و کاهش چشمگیر ویژگی‌های مقاومتی کاغذ می‌باشد. در این تحقیق با استفاده از الیاف بلند کرافت تجاری و نمک‌های آهن و با فرآیند سنتز درجا کاغذ مغناطیسی تولید شد. نانو اکسید آهن حاصل از سنتز درجا عملکردی مانند پر کننده‌ها دارد در نتیجه جهت جلوگیری از کاهش چشمگیر ویژگی‌های مقاومتی در کاغذهای مغناطیسی و کم بودن ماندگاری مواد در کاغذ نهایی، کیتوزان به عنوان افزاینده مقاومت و کمک نگهدارنده در سطوح 0، 10 و 15 درصد استفاده شد. ویژگی‌های کاغذهای مغناطیسی با میکروسکوپ‌های نیروی اتمی و الکترونی روبشی، پراش اشعه ایکس، مغناطیس سنج لرزشی نمونه مورد بررسی قرار گرفت. همچنین شاخص کشش و شاخص پارگی در نمونه‌های کاغذ مغناطیسی تعیین شد. نتایج حاصل از بررسی میکروسکوپی نشان داد که اندازه ذرات نانو مگنتیت در محدوده 1 تا 84 نانومتر بوده و مواد مغناطیسی کاملا سطح الیاف را پوشانده است. همچنین با افزایش مقدار کیتوزان درجه بارگذاری الیاف و اشباع مغناطیسی نمونه‌ها افزایش یافته به‌علاوه کاغذ مغناطیسی ساخته شده از خود خاصیت سوپر پارا مغناطیس نشان داده‌اند. نتایج بررسی ویژگی‌های مقاومتی کاغذ نشان داد که افزودن کیتوزان تا سطح 10 درصد سبب افزایش مقاومت به پارگی و کشش شده ولی افزایش آن تا سطح 15 درصد سبب کاهش این مقاومت ها شده است. | ||
| کلیدواژه‌ها | ||
| اشباع مغناطیسی؛ کاغذ مغناطیسی؛ کیتوزان؛ نانو مگنتیت | ||
| عنوان مقاله [English] | ||
| The dual function of chitosan on improving the retention of iron oxide nanoparticles and the mechanical strength of magnetic paper produced by in situ synthesis | ||
| نویسندگان [English] | ||
| shaghayegh rezanezhad1؛ Hossein Resalati3؛ Seyed Majid Zabihzadeh4؛ | ||
| 1Ph.D. Student of pulp and paper Industry, Agricultural Sciences and Natural Resources of Sari University | ||
| 3Professor, Department of Wood and Cellulose products. Faculty of Natural Resources, Sari University of Agricultural Sciences and Natural Resources | ||
| 4Associate Professor, Department of Wood and Cellulose products. Faculty of Natural Resources, Sari University of Agricultural Sciences and Natural Resources | ||
| چکیده [English] | ||
| The most important challenges of using minerals and fillers in the papermaking process are low retention and sharp reduced paper strength properties. In this research, magnetic papers were synthesized using commercial kraft fibers and iron salts. Nano-iron oxide has the same performance as fillers, as a result, to prevent reducing strengths properties and retention of material in the final paper, chitosan uses as a strength agent and retention aid at 0, 10 and 15% levels. Characteristics of magnetic papers were investigated by atomic force microscope, scanning electron microscope, X-ray diffraction and vibration sample magnetometer. Tensile index and tear index were also determined in magnetic paper samples. The results of the microscopic examination showed that the magnetite nanoparticles were in the size range of 1 to 84 nm and the magnetic materials completely covered the fibers surface. Also, increasing chitosan content, increased the degree of loading and magnetic saturation of the samples. The magnetic paper samples had super para magnetic behavior. The results showed that adding chitosan at 10% increased tear and tensile strength but 15% chitosan decreased the strengths properties of magnetic paper. | ||
| کلیدواژه‌ها [English] | ||
| Magnetic Saturation, Magnetic Paper, Chitosan, Nano Magnetite | ||
| مراجع | ||
|
-Akbarifar, Z., 1389. Effect of Surface Oxidation and Clay Nanoparticles as Fillers on the Properties of Layer Boards. M.Sc. Thesis, University of Tehran. Iran. -Arantes, A.C.C., Almeida, C.D.G., Dauzacker, L.C.L., Bianchi, M.L., Wood, D.F., Williams, T.G., Orts, W.J. and Tonoli, G.H.D., 2017. Renewable hybrid nanocatalyst from magnetite and cellulose for treatment of textile effluents. Carbohydrate Polymers, 163: 101 – 107. -Asna Ashari Ivari, H. and Arabi, V.H., 2013. Synthesis of iron oxide magnetic nanoparticles by in situ method and evaluation of the effect of concentration ratio of reactive materials on particle size and magnetic properties. Journal of Ceramic Science and Engineering, 2 (1): 77 – 84. -Azad Fallah, M., Moradian, K., Mousavi Pajouh, H., Hadilam, M. and Amini, A., 2013. Use of non-bleached Bagas fibers in magnetic paper making. Forest and Wood Products, 67 (4): 667 – 675. -Bani Asadi, M., Tajabadi, M., Nourbakhsh, M. and Kamali, M., 2015. Nuclear-shell synthesis and characterization with superparamagnetic nuclear magnetite and bright polyamide (PAMAM) shell. Journal of Applied Research in Chemistry, 8 (3): 51 – 63. -Cao, Sh. L., Xu, H., Li, X., Lou, W.Y. and Zong, M., 2015. Novel papain mgnetic nanocrystalline cellulose nano – biocatalyst: a highly efficient biocatalyst for dipeptide biosynthesis in deep eutectic solvents. ACS Sustainable Chemistry Engineering. DOI: 10.1021 /acssuschemeng. -Carrazana-Garcia, J.A., Lopez-Quintela, M. and Rivas, J., 1995. Ferrimagnetic paper obtained by in situ synthesis of substituted ferrites. IEEE Transactions on Magnetics, 31: 3126 –3130. -Chia, C. H., Zakaria, S., Nguyen, K.L. and Abdullah, M., 2008. Utilization of unbleached kenaf fibers for preparation of magnetic paper. Industrial Crops and Products, 28: 330 – 339. -Chin, S.F., Binti Romainor, A.N. and Pang, S.C., 2014. Fabrication of hydrophobic and magnetic cellulose aerogel with high oil absorption capacity. Materials Letter, 115: 241 – 243. -Faraji, M. and Fadavi, GH. 2013. Applications of Magnetic Nanoparticles in Food Science and Technology. Iranian Journal of Nutrition Sciences and Food Technology, 8 (2): 239 – 252. -Fragouli, D., Bayer, I., Di Corato, R., Brescia, R., Bertoni, G., Innocenti, C., Gatteschi, D., Pellegrino, T., Cingolani, R. and Athanassiou, A., 2012. Superpapramgnetic cellulose fiber networks via nanocomposite functionalization. Journal of Materials Chemistry, 22: 1662 – 1666. -Gnanaprakash, G., Mahadevan, S., Jayakumar, T., Kalyanasundaram, P. and Philip, T., 2007. Effect of initial pH and temperature of iron salt solutions on formation of magnetite nanoparticles. Materials Chemistry and Physics, 103: 168 – 175. -Hubbe, M.A., 2014. Prospects for maintaining strength of paper and paperboard products while using less forest resources: A review. Bioresoures, 9: 1634 – 1763. -Kaco, H., Waznah, Kh., Jaafar, N. and Gan, Y.S., 2017. Preparation and characterization of Fe3O4 / Regenerated cellulose membrane. Sains malaysiana, 46 (4): 623 – 628. -Karami, Z. and Soleimani, A., 2013. A review of antibacterial cotton fibers. Journal of Studies in the Color World 3: 43 – 51. -Khalafalla, S.E. and Reimers, G.W., 1980. Preparation of Dilution-Stable Aqueous Magnetic Fluids. IEEE Transactions on Magnetics, 16: 178 – 183. -Li, Y., Zhu, H., Gu, H., Dai, H., Fong, Zh., Weadock, J.N., Gou, Zh. and Hu, L., 2013. Strong transparent magnetic nanopapper prepared by immobilization of Fe3O4 nanoparticles in a nanofibrillated cellulose network. Journal of Materials Chemistry A, 1: 15278 – 15283. -Liu, Sh., Zhou, J. and Zhang, L., 2011. In situ synthesis of plate-like Fe2o3 nanoparticles in porous cellulose films with obvious magnetic anisotropy. Cellulose, 18: 663 – 673. -Long, Z., Li, H.F., Yang, X. and Liang, H.N., 2009. Study on preparation and characterization of magnetic paper with bleached chemical pulp. 2nd international congress on image and signal prcessinng, Tianjin, China, 987(1): 4131 - 4244. -Mahdieh, A., Mahdavian, A., Farhadnejad, H. and Salehi Mobakheh, H., 2015. Introduction to magnetic nanoparticles, their synthesis methods and their applications. Nanoscience, 41: 25 – 35. -Mashkor, M., Tajvidi, M. Kimura, T., Kimura, F. and Ebrahmi, Gh., 2011. Fabricating unidirectional magnetic papers using permanent magnets to align magnetic nanoparticles covered natural cellulose fibers. Bioresources, 6(4): 4731 – 4738. -Marchessault, R. H., Rioux, P. and Louis, R., 1992. Magnetic cellulose fibers and paper: preparation, processing and properties. Polymer, 33(19): 4024 - 4028. -Marchessult, R.H., Bremner, G. and Chauve, G., 2006. Fishing for proteins with magnetic cellulosic nanocrystals. American chemical society, Acs symposium series, Washington, DC, chapter 1, 15 pp. Mohamed, A.Z., Zakaria, S., Shamsudin, R. and Abdullah, M., 2010. Cationic starch as a dry strength agent in magnetic papermaking. Sains Malaysiana, 39 (2): 239 – 242. -Mohammad Alizadeh Hanjani, M., Qasemi, A. and Monshi, A., 2013. Influence of Synthesis Temperature on Properties of Magnetic Iron Oxide Nanoparticles in situ Method. Modern Processes in Materials Engineering, 6 (3): 77 – 83. -Molai, M., Azad Fallah, M., Hamza, Y. and Gods, C.F., 2015. The effect of chitosan coating on the barrier and resistance properties of wrapping paper. Iranian Journal of Wood and Paper Science Research, 30 (2): 340 – 330. -Olsson, R.T., Azizi, M. A. S., Salazar, G., Belora, L., Strom, V., Berglund, L. A., Ikkala, O., Nogues, J. and Gedde, U. W., 2010. Making flexible magnetic aerogel and stiff magnetic nanopaper using cellulose nanofibrils as templat. Nature Nanotechnology, 5: 584 – 595. -Orand, M., 2106. Influence of Zein and Chitosan Coating on Strength and Barrier Properties of Liner board. M.Sc. Thesis, Sari Agricultural and Natural Resources University. Iran. -Rashid, M., Abdul ghafur, M., Sharafat, K.M., Minami, H., Miah, M.J. and Ahmad, H., 2017. Biocompatible microcrystalline cellulose particles from cotton wool and magnrtization via a simple in situ co-precipitation method. Carbohydrate Polymers, 170: 72 – 79. -Small, A.C. and Johnston, J.H., 2009. Novel hybrid materials of magnetic nanoparticles and cellulose fibers. Journal of Coloid and Interface Science, 331:122 – 126. -Wu, W.B., Jing, Y., Gong, M.R., Zhou, X. F. and Dai, H.Q., 2011. Preparation and properties of magnetic cellulose fiber composites. Bioresources, 6(3): 3396 – 3409. -Xiong, R., Lu, C. Wang, Y., Zhou, Z. and Zhang, X., 2013. Nanofibrillated cellulose as the support and reductant for the facile synthesis of Fe3O4/Ag nanocomposites with catalytic and antibacterial activity. Journal of Materials Chemistry A, 1: 14910 – 14918. -Zarnegar, Z. and Safari, J., 2010. Magnetic intelligence of nanoparticles. Journal of Nanotechnology, 7(156): 29 – 35. -Zakaria, S., Ong, B.H. and Vande Ven, T.G.M., 2004. Lumen loading magnetic paper l: flocculation. Colloids and surfaces A: phisicochem Engineering, Aspect 251: 1 – 4. -Zakaria, S., Ong, B.H., Ahmad, S.H., Abdullah, M. and Yamauchi, T., 2005. Preparation of lumen – loaded kenaf pulp with magnetite (Fe3O4). Materials Chemistry and Physics, 89: 216 – 220. | ||
|
آمار تعداد مشاهده مقاله: 507 تعداد دریافت فایل اصل مقاله: 374 |
||