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ارتقاء کارایی جذب خاک اره بوسیله‌ی امواج فراصوت: بهینه‌سازی توسط روش سطح پاسخ، مطالعات سینتیک و ترمودینامیک | ||
| تحقیقات علوم چوب و کاغذ ایران | ||
| مقاله 107، دوره 34، شماره 1 - شماره پیاپی 66، اردیبهشت 1398، صفحه 12-26 اصل مقاله (1.03 M) | ||
| نوع مقاله: مقاله پژوهشی | ||
| شناسه دیجیتال (DOI): 10.22092/ijwpr.2019.124486.1509 | ||
| نویسندگان | ||
| سید حسن شریفی* ؛ سلطنت آرچین؛ لیلا آقانقی فر | ||
| گروه مهندسی چوب و کاغذ، دانشکده منابع طبیعی، دانشگاه علوم کشاورزی و منابع طبیعی ساری، ساری، ایران | ||
| چکیده | ||
| Dor:98.1000/1735-0913.1398.34.16.66.1.1575.1603 یکی از مهمترین منابع آلودگی محیط زیست رنگ ناشی از فاضلاب صنایع رنگ می‌باشد که برای انسان و محیط زیست مخاطراتی ایجاد می‌کند. لذا هدف از این مطالعه، بررسی کارایی حذف رنگ متیلن‌بلو از محیط‌های آبی بوسیله‌ی خاک اره با استفاده از امواج فراصوت توسط روش پاسخ سطح می‌باشد. از آزمایشات ناپیوسته به‌منظور ارزیابی اثر غلظت رنگ، زمان فراصوت، دوز جاذب و pH در حذف رنگ از محیط‌های آبی استفاده شـد. در آزمایشـات از روش پاسـخ سطح به‌منظور ارزیابی اثرات متقابل این متغیرها استفاده شد. غلظت رنگ نمونه‌ها با استفاده از اسپکتروفتومتر در طول موج 664 نانومتر اندازه‌گیری شد. نتایج نشان داد که مقادیر پارامترهای بهینه برای دستیابی به حداکثر بازده حذف رنگزا، غلظت اولیه رنگزا 20 میلی‌گرم بر لیتر، زمان واکنش 8 دقیقه، مقدار جاذب 4 گرم بر لیتر وpH اولیه‌ی 9 می‌باشند. بیشترین و کمترین درصد حذف رنگ به‌ترتیب 29/92 و 5/47 درصد حاصل شد. آزمون آنالیز واریانس نشان داد که مدل نمایی، بهترین مدل برای تبیین برهم‌کنش متغیرهای مطالعه می‌باشد. بر اساس نتایج آنالیز واریانس مقدار بالای ضریب تعیین نشان می‌دهد که مقادیر آزمایشگاهی با مقادیر پیش‌بینی شده تطابق خوبی دارند (9486/0=2R). علاوه بر این آنالیز آماری نتایج نشان داد که در محدوده مطالعه شده، pH و مقدار جاذب اثر قابل توجهی روی راندمان حذف رنگزا دارند. داده‌های انرژی آزاد گیبس و آنتالپی نشان‌دهنده فرآیند خودبخودی و گرماگیر می‌باشد. همچنین بررسی مدل‌های سینتیکی شبه مرتبه اول و دوم نشان داد که فرآیند با مدل سینتیکی شبه درجه دوم مطابقت دارد. | ||
| کلیدواژه‌ها | ||
| رنگ متیلن بلو؛ جذب سطحی؛ فراصوت؛ روش پاسخ سطح؛ طرح مرکب مرکزی؛ سینتیک و ترومودینایک جذب | ||
| عنوان مقاله [English] | ||
| Improved adsorption performance of sawdust by ultrasonic wave: Optimization through response surface methodology, kinetic and thermodynamic studies | ||
| نویسندگان [English] | ||
| Seyed Hassan Sharifi؛ Saltanat Archin؛ Leila Aghanaghifar | ||
| Wood and Paper Science Department, Faculty of Natural Resources, Sari Agricultural Sciences and Natural Resource University Sari, Iran | ||
| چکیده [English] | ||
| DOR:98.1000/1735-0913.1398.34.16.66.1.1575.1603 One of the most important sources of environmental pollution is dye from industrial wastewater which is harmful for human health and environment. Therefore, the aim of this study was to evaluate removal of Methylene Blue (MB) dye from aqueous solutions by straw using ultrasonic wave with response surface methodology. The batch experiment was conducted to evaluate the effect of dye concentration, contact time, adsorbent dosage and pH on dye removal from aqueous solution. Response surface methodology was applied to appraise the effect of these different variables. The dye concentration in the solutions was measured by spectrophotometer at the wavelength of 664 nm. The results showed that the optimum parameter values for maximum color removal efficiency were: dye concentration 20 mg/L, reaction time 8 min, dose of adsorbent 4 g/L and pH=9. The Maximum and minimum dye removal were obtained 92.29 and 47.5 percent, respectively. Analysis of variances test showed that the quadratic model was the best model to explain the interaction of variables. Based on analysis of variance (ANOVA), the coefficient of determination value (R2 =0.9116) was high, showing that the experimental values fitted well with the predicted values. In addition, the statistical analysis of the results indicated that in the range studied, dose of adsorbent and pH had a significant effect on color removal efficiency. The Gibbs free energy and enthalpy data verified its spontaneous and endothermic nature. In addition, survey of pseudo first and second order kinetics models presented that the adsorption process was compatible to pseudo-second order kinetics equation. | ||
| کلیدواژه‌ها [English] | ||
| Methylene Blue dye, Adsorption, Ultrasonic wave, response surface methodology, Central composite design, Adsorption kinetic and thermodynamic | ||
| مراجع | ||
|
Aksu, Z., 2005. Application of biosorption for the removal of organic pollutants: a review. Process Biotechnology, 40: 997-1026.
Asfaram, A., Ghaedi, M., Yousefi, F. and Dastkhoon, M., 2016. Experimental design and modeling of ultrasound assisted simultaneous adsorption of cationic dyes onto ZnS: Mn-NPs-AC from binary mixture, Ultrasonics Sonochemistry, 33: 77–89.
Azad, F.N., Ghaedi, M., Dashtian, K., Hajati, S. and Pezeshkpour, V., 2016. Ultrasonically assisted hydrothermal synthesis of activated carbon–HKUST-1-MOF hybrid for efficient simultaneous ultrasound-assisted removal of ternary organic dyes and antibacterial investigation: Taguchi optimization, Ultrasonics Sonochemistry, 31: 383–393.
Abechi, S. E., Gimba, C. E., uziaru, A., Ndukwe, I. G. (2006). Comparative studies on adsorption of methylene blue by sawdust and walnut shells carbon coated by ZnO, Science World Journal, 1(1): 33-35.
Batzias, F.A. and Sidiras, D.K., 2007. Simulation of dye adsorption by beech sawdust as affected by pH. Journal of Hazardous Materials, 141(3): 668-679.
Bazrafshan, E., Zarei, A.A., Nadi, H. and Zazouli, M.A., 2014. Adsorptive removal of methyl orange and reactive red 198 dyes by Moringa Peregrina ash. Indian Journal of Chemical Technology, 21(2): 105-113.
Bazarafshan, E., 2017. Efficiency of combined processes of coagulation and modified activated bentonite with sodium hydroxide as a biosorbent in the final treatment of leachate: kinetics and thermodynamics. Journal of health research in community, 3(3):6-17.
Beltrame, K.K., Cazetta, A.L., de Souza, P.S.C., Spessato, L., Silva, T. L. and Almeida, V. C., 2018. Adsorption of caffeine on mesoporous activated carbon fibers prepared from pineapple plant leaves. Ecotoxicology and Environmental Safety, 147: 64–71.
Daoud, M., Benturki, O., Kecira, Z., Girods, P. and Donnot, A., 2017. Removal of reactive dye (BEZAKTIV Red S-MAX) from aqueous solution by adsorption onto activated carbons prepared from date palm rachis and jujube stones. Journal of Molecular Liquids, 243: 799–809.
Garg, V.K., Amita, M., Kumar, R. and Gupta, R., 2004. Removal methylene blue from simulated wastewater by adsorption using Indian Rosewood sawdust: a timber industry waste, Dyes and Pigments, 63: 243–50.
Khoshnamvand, N., Ahmadi, S. and Mostafapour, F.K., 2017. Kinetic and isotherm studies on ciprofloxacin an adsorption using magnesium oxide nanoparticles. Journal of Applied Pharmaceutical Science, 7(11):79-83.
Li, Y.H., Wang, S.G., Wei, J.Q., Zhang, X.F., Xu, C.L., Luan, Z.K., Wu, D.H. and Wei, B.Q., 2002. Lead adsorption on carbon nanotubes. Chemical Physics Letters, 357: 263–6.
Liu, H., Yang, S., Ni, Y. (2007). Using dyes for improving the optical properties of highly yield pulps. Pulp & Paper Canada, 108 (10): 25-29.
Lucas, M. and Peres, J., 2007. Degradation of Reactive Black 5 by Fenton/UV and ferrioxalate/H2O2/solar light process. Dyes and Pigments, 74: 622-29.
Maleki, A., Daraei, H., Khodaei, F., Aghdam, K.B., Rezaee, R. and Naghizadeh, A., 2013. Investigation of potato peel based bio-sorbent in reactive dye removal: ANN modeling and GA optimization. Journal of Advances in Environmental Health Research, 1: 21-8.
Mall, I. D., Srivastava, V. C., Agarwal, N. K. and Mishra, I.M., 2005. Removal of congo red from aqueous solution by bagasse fly ash and activated carbon: Kinetic study and equilibrium isotherm analyses. Chemosphere, 61: 492–501.
Mona, S., Kaushik, A. and Kaushik, C.P., 2011. Waste biomass of Nostoc linckia as adsorbent of crystal violet dye: Optimization based on statistical model. International Biodeterioration & Biodegradation, 65: 513-521.
Narbatiz, R.M., R.L. Drost, L. Frenandes and D. ball. (1997). Process for treatment of kraft mill effluent. Water Science and Technology, 35(2-3): 283-290.
Ong, S.T., Keng, P.S., Chong A.W., Lee S.L. and Hung, Y.T., 2010. Tartaric Acid Modified Rice Hull as a Sorbent for Methylene Blue Removal. American Journal of Environmental Sciences, 6(3): 244-248.
Özacar, M. and Sengil, A.I., 2005. Adsorption of metal complex dyes from aqueous solutions by pine sawdust. Bioresource Technology, 96: 791–95.
Ponnusami, V., Vikram, S. and Srivastava, S., 2008. Guava (Psidium guajava) leaf powder: Novel adsorbent for removal of methylene blue from aqueous solutions. Journal of Hazardous Materials, 152(1):276–286.
Rahdar, S. and Ahmadi, S., 2017. Removal of phenol and aniline from aqueous solutions by using adsorption on to Pistacia terebinthus: study of adsorption isotherm and kinetics. Journal of health research in community, 2(4): 35-45.
Rahdar, S., Samani, S. and Ahmadi, S., 2018. Efficiency of Arachis hypogaea Ash in Aniline Adsorption from Aqueous Solution: A Thermodynamic and Kinetic Study. Journal of Health Research in Community, 3(4): 21-32.
Rahimi, A., Hamzeh, Y., Abdolkhani, A., Hejazi, S. and Izadyar, S., 2018. The use of lignocellulosic waste of rice straw for textile dyes adsorption. Iranian Journal of Wood and Paper Industries, 9(3): 397-409.
Roohbakhsh Bidaei, M., Azadfallah, M. and Yarahmadi, R., 2018. Adsorption of rhodamine B dye with activated carbon prepared from beech wood, 289 Iranian Journal of Wood and Paper Science Research, 33(2): 280-289.
Shafiabadi, M., Dashti, A., Tayebi, H.A., 2016. Removal of Hg (II) from aqueous solution using polypyrrole/SBA-15 nanocomposite: Experimental and modeling. Synthetic Metals, 212:154-160.
Sharifi Pajaie, H. and Taghizadeh, M., 2015. Statistical Optimization for Production of Light Olefins in a Fluidized‐Bed Reactor, Chemical Engineering & Technology, 38(5): 931-940.
Sharifi, S. H. and Shoja H., 2018. Optimization of process variables by response surface methodology for methylene blue dye removal using Spruce sawdust/MgO nanobiocomposite. Journal of Water and Environmental Nanotechnology, 3(2): 157-172.
Sobhanardakani, S. and Zadipak, R., 2016. Removal of methyl orange dye from aqueous solutions using NiFe2O4 nanoparticles: equilibriun and kinetic study. Iranian Journal of Health and Environment, 9(2):247- 58 (in Persian).
Somasiri, W., Li, X., Ruan, W. and Jian, C., 2008. Evaluation of the efficacy of upflow anaerobic sludge blanket reactor in removal of colour and reduction of COD in real textile wastewater. Bioresource Technology, 99: 3692-99.
Taherkhani, F., Leili, M., Azar, M.T. and Faradmal, J., 2015. The optimization of aniline adsorption from aqueous solutions by raw Bentonite and Bentonite modified with cationic surfactants using the Taguchi model. Scientific Journal of Hamadan University of Medical Sciences and Health Services, 22(1): 55-64.
Vargas, A. M. M., Cazetta, A. L., Kunita, M. H., Silva, T. L., Almeida, V. C. (2011). Adsorption of methylene blue on activated carbon produced from flamboyant pods (Delonix regia): Study of adsorption isotherms and kinetic models, Chemical Engineering Journal, 168: 722–730.
Ziapour, A., Zare, A. and Bakhshi, M. (2018). Application of Bagasse as adsorbent of acid orange 7 from aqueous solution. Iranian Journal of Wood and Paper Science Research, 33(2): 244-255. | ||
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